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Proposed AASHTO Guide Specification For Highway Construction, 1998
SECTION 713. Concrete Curing Materials and Admixtures
713.04 Lithium Admixtures. - The lithium ion, Li+, in several forms is capable of suppressing deleterious ASR, but different compounds have varying effects on the plastic and hardened properties of concrete. LiNO3 (lithium nitrate) is safe to handle, and has the least effect on concrete properties, while it has the greatest effect in concrete to prevent deleterious ASR. LiNO3 also does not generate hydroxide ions in concrete pore solutions, and therefore does not exhibit a pessimum effect. LiOH (lithium hydroxide) on the other hand is caustic, is a hazardous material, and both LiOH and Li2CO3 (lithium carbonate) exhibit a pessimum effect on deleterious ASR prevention. Lithium salts other than LiNO3 can still be useful depending on the intended application. Test all mixtures under AASHTO M 194 to determine the admixture's affect on the plastic and final hardened concrete properties. Suppress deleterious ASR in concrete using primarily a lithium admixture of a nominal 30 percent by mass aqueous solution of LiNO3 with a density of 1.2 kilogram per liter, or use other forms as shown below.
| LiNO3 aqueous admixture. |
| Constituent |
Limit (percent by mass) |
| LiNO3 (lithium nitrate) |
30% ± 0.5% |
| SO4-2 (sulfate ion) |
0.1% max |
| Cl- (chloride ion) |
0.2% max |
| Na+ (sodium ion) |
0.1% max |
| K+ (potassium ion) |
0.1% max |
| Li2CO3 solid admixture. |
| Constituent |
Limit (percent by mass) |
| Li2CO3 (lithium carbonate) |
99% min |
| SO4-2 (sulfate ion) |
0.4% max |
| Cl- (chloride ion) |
0.1% max |
| Na+ (sodium ion) |
0.2% max |
| K+ (potassium ion) |
0.1% max |
| LiOH·H2O solid admixture. |
| Constituent |
Limit (percent by mass) |
| LiOH (lithium hydroxide) |
55.9% min |
| SO4-2 (sulfate ion) |
0.4% max |
| Cl- (chloride ion) |
0.1% max |
| Na+ (sodium ion) |
0.2% max |
| K+ (potassium ion) |
0.1% max |
| LiOH aqueous admixture. |
| Constituent |
Limit (percent by mass) |
| LiOH (lithium hydroxide) |
8.75% ± 0.25% min |
| SO4-2 (sulfate ion) |
0.4% max |
| Cl- (chloride ion) |
0.1% max |
| Na+ (sodium ion) |
0.2% max |
| K+ (potassium ion) |
0.1% max |
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